February 18, 2010 feature
Can graphene nanoribbons replace silicon?

(麻豆淫院Org.com) -- "Graphene has been the subject of intense focus and research for a few years now," Philip Kim tells 麻豆淫院Org.com. "There are researchers that feel that it is possible that graphene could replace silicon as a semiconductor in electronics."
Kim is a scientist at Columbia University in New York City. He has been working with Melinda Han and Juliana Brant to try and come up with a way to make graphene a feasible replacement for silicon. Toward that end, they have been looking at ways to overcome some of the problems associated with using graphene as a semiconductor in electronic devices. They set forth some ideas for electron transport for graphene in 麻豆淫院ical Review Letters: 鈥Electron Transport in Disordered Graphene Nanoribbons."
鈥淕raphene has high mobility, and less scattering than silicon. Theoretically, it is possible to make smaller structures that are more stable at the nanolevel than those made from silicon,鈥 Kim says. He points out that as electronics continue to shrink in size, the interest in finding viable alternatives to silicon is likely to increase. Graphene is a good candidate because of the high electron mobility it offers, its stability on such a small scale, and the possibility that one could come up with different device concepts for electronics.
There are problems with graphene, though. 鈥淔irst of all, graphene does not have a band gap, and that is essential for semiconductor device operation,鈥 Kim points out. 鈥淧reviously, we found that you can create an energy gap by cutting graphene into strips, creating nanoribbons..鈥 Of course, now that scientists can use nanoribbons to create an energy gap, a new set of challenges has arisen. 鈥淭he gap is not so simple as we first thought. We have new complications to deal with now in the way the energy gap behaves.鈥
Kim and his colleagues discovered that the nanoribbons have a rough edge, creating more scattering than they would like. 鈥淭here is good control up to the nanometer,鈥 he says, 鈥渂ut the control is not as precise at the atomic level.鈥 Another issue is that the nanoribbons sit on a substrate, adding more disorder. 鈥淥ur paper here is mostly concerned with identifying these issues, so that we can better understand how graphene nanoribbons might be used in the future,鈥 Kim insists. 鈥淲e want to understand the nature of the energy gap so that we can perhaps engineer smoother atomic edges and create a better substrate that does not induce disorder potential.鈥
With the knowledge of how to create an energy gap with graphene nanoribbons available, and with some of the properties of the gap identified, it is possible to begin making changes. 鈥淚鈥檓 hopeful that in the future we might be able to use graphene to compete with silicon,鈥 Kim says. 鈥淭he high mobility of graphene makes it a good candidate, and since it is likely to be more stable at the nanoscale, there is real potential. However, we need to be able solve some of these other problems first. But we are well on our way.鈥
More information: Melinda Han, Juliana Brant, and Philip Kim, 鈥淓lectron Transport in Disordered Graphene Nanoribbons,鈥 麻豆淫院ical Review Letters (2010). Available online: .
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